Duplex 2205

Technical Reference Library

Duplex 2205

Wnr. 1.4462 UNS S32205 / S31803 DIN/EN X2CrNiMoN22-5-3

Material Overview

2205 is the benchmark duplex stainless steel — the grade every other duplex alloy on this site gets compared against. Its name is shorthand for its composition: roughly 22% chromium and 5% nickel, backed by about 3% molybdenum and 0.14-0.20% nitrogen. Those four elements are balanced specifically to split the solidified microstructure into close to equal parts austenite and ferrite. That dual-phase structure is the source of everything that makes duplex stainless distinct from the standard 300-series: the austenite islands provide ductility and toughness, while the continuous ferrite network resists chloride stress-corrosion cracking and pitting far better than an all-austenitic structure, and pushes yield strength to roughly double that of 304 or 316 in the annealed condition.

With a PREN (pitting resistance equivalent number) in the mid-30s, 2205 comfortably outperforms 316L in chloride-rich environments while costing meaningfully less than the super duplex grades that push PREN into the 40s. That balance of strength, corrosion resistance, and cost is why 2205 dominates real-world duplex use: offshore platforms and subsea equipment, pressure vessels, pulp and paper processing, desalination plants, and chemical tankers all lean on 2205 as the default duplex specification, reserving super duplex grades for the most aggressive chloride or acidic conditions.

International Designation Equivalents

Standard Designation
UNS S32205 (S31803)
Wnr. (Werkstoffnummer) 1.4462
DIN / EN X2CrNiMoN22-5-3
ASTM A240 (plate/sheet), A276/A479 (bar), A789/A790 (tube/pipe)

Chemical Composition

Element Content
Chromium (Cr) 22.0 – 23.0%
Nickel (Ni) 4.50 – 6.50%
Molybdenum (Mo) 3.00 – 3.50%
Nitrogen (N) 0.14 – 0.20%
Manganese (Mn) 2.00% max
Silicon (Si) 1.00% max
Carbon (C) 0.030% max
Phosphorus (P) 0.030% max
Sulfur (S) 0.020% max

Estimated PREN (Cr + 3.3×Mo + 16×N) is approximately 34-36, roughly double a standard 316L composition.

Machinability Explained

2205's dual-phase structure is the whole story behind its machining behavior. The austenite half of the microstructure work-hardens the same way 304 or 316 does, but nowhere near as aggressively, since it only makes up about half the material instead of all of it. The ferrite half doesn't work-harden much at all — but it's noticeably harder and stiffer than austenite, and it's what makes 2205 a genuinely demanding material to cut. The net effect is a material that generates higher cutting forces and more heat at the tool edge than any standard austenitic stainless, even though it's less prone to the classic 300-series problem of a hardened skin building up under a dull tool.

Because both phases have to be sheared cleanly on every pass, tool rigidity and edge support matter as much as sharpness. A tough, wear-resistant coated carbide grade generally beats a fine-edged, aggressive geometry on 2205 — the priority is surviving sustained mechanical load and heat rather than minimizing work hardening. Coolant is important for pulling heat out of the cutting zone, since 2205's thermal conductivity is lower than carbon steel and only moderately better than 316L. Chip control tends to be more predictable than on fully austenitic grades because the ferrite content shortens the chip, but a rigid, low-deflection setup remains the single biggest factor in getting consistent tool life on this alloy.

Recommended Cutting Speeds

Operation Vc (m/min) Vc (SFM)
Turning 90 – 125 295 – 410
Milling 60 – 80 195 – 260
Parting 40 – 55 130 – 180
Grooving 50 – 70 165 – 230
Drilling 25 – 35 80 – 115

Values assume favorable cutting conditions: a well-matched insert grade, rigid tool and workpiece clamping, short tool overhang, and adequate coolant. Reduce speeds for interrupted cuts or thin-wall parts prone to deflection.

Recommended FM Carbide Grades by Operation

Turning

Grade Coating ISO Application Range
FM2553 CVD M20 – M30
FM199 PVD M30

Parting / Grooving

Grade Coating ISO Application Range
FM2543 CVD M20
FM2553 CVD M30

Milling

Grade Coating ISO Application Range
FM125 PVD M20 – M35

Ready to cut Duplex 2205? Shop FM Carbide inserts matched to this alloy's turning, parting, grooving, and milling requirements.

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Recommended Insert Cutting-Edge Geometry

Parameter Value
Honing Size 0.03 – 0.05 mm / 0.001 – 0.002"
Rake Angle 6° – 9°
Land Angle Positive
Land Width 0.20 – 0.30 mm / 0.008 – 0.012"