Material MAR-M 322

Technical Reference Library

MAR-M 322

Type Cast Co-Base Superalloy Cobalt ~60% Chromium ~21.5%

Material Overview

MAR-M 322 is a cast cobalt-base superalloy in the same Martin Metals family as MAR-M 302 and MAR-M 509, developed for high-strength turbine vane applications where components see sustained exposure to combustion-gas temperatures. Cobalt makes up roughly 60% of the alloy, with chromium at approximately 21.5% providing oxidation and hot-corrosion resistance. The DIN designation CoCr22W9TaZrNb identifies the alloy's strengthening system: tungsten (9%) for solid-solution strengthening plus tantalum, zirconium, and niobium additions that combine with carbon to form a dense carbide network at grain boundaries.

That carbide network is the source of MAR-M 322's high strength at elevated temperature, and it is also what makes the alloy demanding to cut. A titanium addition near 1% and roughly 1% carbon round out the composition, and a small aluminum addition (~0.8%) contributes to the alloy's overall oxidation resistance alongside chromium. As with other cast, carbide-strengthened cobalt superalloys, shops should expect this material to behave more aggressively toward tooling than a comparable wrought cobalt or nickel alloy at the same nominal hardness.

Chemical Composition

Element Amount
Cobalt (Co) 60%
Chromium (Cr) 21.5%
Tungsten (W) 9%
Titanium (Ti) 1%
Carbon (C) 1%
Aluminum (Al) 0.8%
Silicon (Si) 0.1%
Manganese (Mn) 0.1%

Tantalum, zirconium, and niobium are named in the DIN CoCr22W9TaZrNb designation as carbide-forming additions but were not broken out with individual percentages in the source composition record, and are therefore not listed as separate line items above.

Machinability Explained

MAR-M 322's carbide-strengthened cast structure puts it in the same demanding category as other Ta/Zr-bearing cobalt superalloys. The tantalum, zirconium, and niobium carbides distributed through the cobalt-chromium-tungsten matrix are extremely hard relative to the surrounding metal, and the cutting edge alternates between shearing the comparatively ductile matrix and impacting these hard carbide particles on every revolution. That mechanical mismatch is the primary driver of accelerated, often unpredictable flank wear on this grade.

Hot-hardness retention is excellent by design - it is what makes MAR-M 322 valuable as a turbine vane material - but it also means the alloy stays hard and abrasive across the entire practical cutting-speed range, with no useful thermal softening window the way many steels exhibit. Cobalt-matrix work hardening adds a second layer of difficulty: any rubbing, dwell, or light chip load produces a work-hardened skin that resists the next pass more than the parent material did.

Conservative cutting speeds, sharp positive-rake ground carbide geometry, rigid setups with minimal tool overhang, and continuous, generous coolant delivery are the baseline requirements for machining this alloy successfully. Because carbide-strengthened cast structures can wear tools unevenly, monitor edge condition closely and index proactively rather than pushing an insert until visible failure.

Recommended Cutting Speeds

Application Vc (m/min) Vc (SFM)
Turning 25-75 80-250
Milling 20-55 70-180
Parting 15-50 50-160
Grooving 20-65 70-210
Drilling 20-65 70-210

General starting-point ranges for cast, carbide-strengthened Co-based superalloys. Run at the low end of these ranges until tool wear is characterized for your specific setup.

Recommended FM Carbide Grades by Operation

Turning

Grade Coating ISO Application Range
FM524 CVD S05 - S10
FM2533 CVD S15

Parting / Grooving

Grade Operation Coating ISO Application Range
FM2543 Parting CVD S20
FM2553 Parting CVD S30
FM2533 Grooving CVD S10

Milling

Grade Coating ISO Application Range
FM125 PVD S15 - S35

Ready to cut MAR-M 322? Shop FM Carbide inserts engineered for cast, carbide-strengthened cobalt superalloys.

Shop Turning & Grooving Inserts Shop Milling Inserts

Recommended Insert Cutting-Edge Geometry

Honing Size 0.02-0.04 mm / 0.001-0.0016"
Rake Angle 13° - 18°
Land Angle Neutral
Land Width 0.10-0.20 mm / 0.004-0.008"
Ground Insert Recommended