Steel 904 L

Technical Reference Library

Steel 904L (Superaustenitic Stainless)

Wnr. 1.4539 UNS N08904 DIN/EN X1CrNiMoCu25-20-5

Material Overview

904L is a high-alloy superaustenitic stainless steel, carrying roughly 20-21% chromium, 24-25% nickel, and 4.3-4.5% molybdenum — well beyond standard 300-series levels across the board. What sets 904L apart from other high-alloy austenitics, though, is a deliberate 1.2-2.0% copper addition, an alloying choice that is unusual among stainless grades and is specifically there to improve resistance to sulfuric acid. That copper addition, combined with the heavy chromium/nickel/molybdenum base, gives 904L excellent resistance across a very wide range of sulfuric and phosphoric acid concentrations and temperatures — conditions that would rapidly attack 316L and even most duplex grades.

Very low carbon content (0.02% max) keeps 904L resistant to sensitization during welding, so it can be welded and put into acid service without post-weld heat treatment. It shows up in sulfuric and phosphoric acid production and handling equipment, flue-gas desulfurization systems, bleaching equipment in pulp and paper processing, and other aggressive chemical environments where standard austenitic or even duplex stainless grades fall short. Like all austenitic grades it is not hardenable by heat treatment, but its high alloy content — nickel and molybdenum in particular — gives it a notably stronger work-hardening response under mechanical action than standard 300-series stainless, which is the key thing to plan around at the machine.

International Designation Equivalents

Standard Designation
Wnr. (Werkstoffnummer) 1.4539
DIN / EN X1CrNiMoCu25-20-5
UNS N08904
SS 2562
JIS SUS 904L
ASTM A240 / A276

The legacy page listed this material's UNS number as S30601 — that is actually the UNS code for a different alloy (610/611 family, a high-silicon nitric acid grade covered elsewhere in this library), copy-pasted in by mistake. The correct UNS number for 904L, N08904, is used here.

Chemical Composition

Element Content
Nickel (Ni) 23.0 – 28.0%
Chromium (Cr) 19.0 – 23.0%
Molybdenum (Mo) 4.0 – 5.0%
Copper (Cu) 1.0 – 2.0%
Manganese (Mn) 2.00% max
Silicon (Si) 1.00% max
Carbon (C) 0.02% max
Phosphorus (P) 0.045% max
Sulfur (S) 0.035% max

The legacy page's composition was close for Cr/Ni/Mo but omitted copper entirely — the alloying addition that gives 904L its signature sulfuric-acid resistance. Added here.

Machinability Explained

904L is noticeably harder to machine than standard 300-series stainless, and the reason is its alloy content, not its hardness number. Nickel and molybdenum both raise the shear strength of the material in the cutting zone and intensify work hardening under a rubbing or dull tool — 904L work-hardens faster and more severely than 304 or even 316, so the margin for error with a marginal edge is smaller. Low thermal conductivity, already an issue on standard austenitics, is compounded by the heavier alloy content, concentrating cutting heat at the tool tip and accelerating crater wear on tooling that isn't built for high-alloy service.

Sharp, positive-rake carbide is not optional on this grade — it's the difference between shearing the material cleanly and burnishing a hardened skin into the surface that the next pass then has to fight through. Feed rates need to stay consistently high enough to cut beneath any hardened layer, and tool changes should happen on a predictable schedule rather than by chasing visible wear, since a dulling edge on 904L both work-hardens the surface and loses cutting geometry at the same time. Rigid setups and minimal tool overhang matter more here than on standard stainless, since the higher cutting forces this alloy generates will deflect a marginal setup and produce chatter that further work-hardens the surface.

Chip control follows the austenitic pattern but is more demanding — expect tough, high-strength chips that need a chipbreaker geometry specifically suited to high-alloy superaustenitic stainless rather than a general 300-series insert. Adequate, well-directed coolant is essential to manage both the heat concentration and the elevated cutting forces this grade generates.

Recommended Cutting Speeds

Operation Vc (m/min) Vc (SFM)
Turning 90 – 120 300 – 390
Milling 55 – 75 180 – 250
Parting 35 – 45 115 – 150
Grooving 50 – 65 165 – 215
Drilling 25 – 35 80 – 115

Speeds run well below standard 304/316-type stainless because of 904L's much higher nickel and molybdenum content and stronger work-hardening tendency. Values assume favorable conditions: a well-matched insert grade, rigid setup, short tool overhang, and adequate coolant. Reduce further for interrupted cuts or thin-wall parts prone to deflection.

Recommended FM Carbide Grades by Operation

Turning

Grade Coating ISO Application Range
FM324 PVD M10 – M20
FM2553 CVD M30

Parting Off

Grade Coating ISO Application Range
FM2543 CVD P20
FM2553 CVD M30

Grooving

Grade Coating ISO Application Range
FM2533 CVD P10

Milling (Indexable)

Grade Coating ISO Application Range
FM125 PVD M15 – M35

Ready to cut 904L? Shop FM Carbide inserts matched to this superaustenitic alloy's turning, parting, grooving, and milling requirements.

Shop Turning & Grooving Inserts Shop Milling Inserts

Recommended Insert Cutting-Edge Geometry

Parameter Value
Honing Size 0.03 – 0.05 mm / 0.001 – 0.002"
Rake Angle 9° – 11°
Land Angle Positive
Land Width 0.20 – 0.30 mm / 0.008 – 0.012"