Steel AL 29-4C

Technical Reference Library

AL 29-4C

UNS S44735 Type Superferritic Stainless Cr ~29%

Material Overview

AL 29-4C is a superferritic stainless steel, UNS S44735, built around an unusually high 29% chromium and 4% molybdenum content with iron making up the balance. Because it solidifies and stays ferritic (body-centered cubic) rather than austenitic, it does not work-harden the way 300-series stainless does and it is mildly magnetic. What makes the "superferritic" family possible at all is an extremely tight limit on carbon and nitrogen — the interstitial elements that otherwise make high-chromium ferritic stainless brittle and prone to sensitization at the grain boundaries, especially near a weld. By keeping carbon and nitrogen very low, AL 29-4C retains enough toughness and weldability to be used as mill-annealed sheet, tube, and plate rather than just a cast or coarse-grained product.

The payoff for that alloy content is corrosion resistance that rivals or exceeds many high-nickel austenitic and superaustenitic grades, particularly against chloride pitting and crevice attack, without the nickel cost. That combination makes AL 29-4C a standard choice for seawater-cooled condenser and heat exchanger tubing, brackish and salt water piping, and other chloride-heavy service in power generation and chemical processing where 316 or even 6-Mo superaustenitics would eventually pit.

International Designation Equivalents

Standard Designation
UNS S44735

Only the UNS designation could be verified against current standards; other cross-references were not confirmed and are omitted rather than guessed.

Chemical Composition

Element Amount
Chromium (Cr) ~29%
Molybdenum (Mo) ~4%
Nickel (Ni) ≤0.5%
Manganese (Mn) ≤0.5%
Silicon (Si) ≤0.35%
Carbon (C) ≤0.025%
Iron (Fe) Balance

Carbon and nitrogen are held to very low "low-interstitial" limits by design — this is what gives the alloy its weldability and toughness despite the very high chromium and molybdenum content.

Machinability Explained

Because AL 29-4C is ferritic rather than austenitic, it does not work-harden as aggressively as 304, 316, or the 6-Mo superaustenitics, and its chip tends to be somewhat more manageable. That said, this is still a very high-alloy stainless — nearly 30% chromium plus 4% molybdenum — and high total alloy content drives up cutting forces and abrasive tool wear regardless of crystal structure. Expect gummy chip flow and a tendency to smear rather than shear cleanly if the edge is dull or the feed is too light, similar to what you'd see machining a high-alloy austenitic grade.

Low thermal conductivity is also a factor here, as it is with most stainless: heat concentrates at the cutting edge instead of dissipating into the chip, so coolant and a sharp, positive-rake geometry matter more than they would on a plain carbon or low-alloy steel. Keep feeds firm enough to cut underneath any work-hardened or smeared skin left by the previous pass, and favor a wear-resistant coated grade to handle the abrasive wear from the high chromium-molybdenum content.

Recommended Cutting Speeds

Application Vc (m/min) Vc (SFM)
Turning 155-195 510-640
Milling 95-125 310-410
Parting 60-80 200-260
Grooving 90-120 300-390
Drilling 45-55 150-180

Values assume favorable conditions: a well-matched insert grade, rigid tool and workpiece clamping, good raw material quality, short tool overhang, and adequate coolant.

Recommended FM Carbide Grades

Turning

Grade Coating ISO Application Range
FM324 PVD M10-M20
FM2553 CVD M30

Parting / Grooving

Grade Coating ISO Application Range
FM2543 CVD P20
FM2553 CVD M30
FM2533 CVD P10

Milling

Grade Coating ISO Application Range
FM125 PVD M15-M35

Recommended Insert Cutting Edge Geometry

Parameter Value
Honing Size 0.03-0.05 mm / 0.001-0.002"
Rake Angle 9°-11°
Land Angle Positive
Land Width 0.20-0.30 mm / 0.008-0.012"